I was at home with our first daughter for about 3 months before going back to work too. Whenever I'd give her to him for me to have a few minutes to breath, she would just wail and wail.
Obviously, he was really upset by it too. He said he wanted to make her the priority, and wanted to start doing her bath and bedtime routine. That meant that I had to take the backseat. He would start up, and I would assist in whatever way he wanted (sometimes it was better if she didn't know I was assisting, sometimes it was okay). But that would usually give me time to at least put some dishes in the dishwasher or put in a load of laundry or something.
Work on the pacifier thing. I know a lot of people don't like them, but babies have a natural instinct/reflex (whatever you want to call it) to suck on something (eg. pacifier).
It's one of those "spin the wheel" sort of things too:
Is she too hot? Too cold? Is she hungry? (Growth spurt's possibly at 3 weeks? Definitely at 6 weeks.) Is she gassy? (Mylicon?) Does she have to poop? Is she tired?
Sometimes spinning the wheel helps - but he needs to establish a routine while you're gone too. Maybe once you leave, he gives her a bath. Gets her ready for bed - gives her a bottle. Reads a story, whatever.
Kids also "sense the tension" very well. If he's tense, she's going to be tense. Maybe to help him chill, while he carries her around, he sings a song to her. I'd carry around my daughters just saying to a beat, "Here we go, a-here we go, here we go....we're gonna go, gonna go downstairs..." and soon enough, they'd start bopping along with me.
Once she gets used to being around daddy and getting used to the routine and daddy-time, she'll be fine...in fact, she may "switch sides" and start wanting him at night! (THat's what happened with our 20 month old!)
Good luck!