I grew up in Scottsboro, Alabama. It's a somewhat small city with an excellent school system. It is about 10 hours from Orlando, according to Google Maps.
Guntersville, AL, is also a good area. Madison, AL, is good too, though a larger city (not as large as Huntsville next door). Madison has a great school system as well. We are in the process of trying to move there from Huntsville so that our daughter can go to school there. (Don't put your kids in Huntsville school system......)
There are other good places around the North Alabama area. I love it here :)