The area around Midwestern is called the Arrowhead Area and is in north Glendale ( north and south of the 101). There are some great neighborhoods all around. The one just east of Midwestern is great, quiet and has a park and is walking distance. It is called Carmel Park, and Carmel Cove. The local library is very nice and is also walking distance from this neighborhood and it has a storytime for kids. They also have passes that you can check out to visit museums, etc. for free.There are nice neighborhoods to the west side as well. Midwestern is just south of the 101. The neighborhoods north of the 101 tend to be a little more expensive with HOA's. Pluses and minuses with those. The cities of Glendale and Peoria are next to each other and are both long and narrow. Stay to the north ends of both cities ( north of Peoria Avenue). The south side of the 101 is nice ( I think another person mentioned it was not so nice - they may have been farther south of downtown Glendale, which would be too far for you to drive anyway). The schools in north Peoria and north Glendale ( Deer Valley school district) are both good. This area has great highway access as well. Someone mentioned the town of Surprise. While it is a nice town to the west, access to get there is very congested with traffic and would take a 1/2 hour to get there with good traffic.
Phoenix is pretty easy to figure out....Central Ave is in the center and goes north/south. The roads that are parallel to the east are all streets ( numbers increase as you go to the east) and the Avenues( parallel) are to the west of Central and the numbers increase as you go farther west. Midwestern is at 59th Ave.
I haven't needed daycare, but there is a place north of the 101 at 67th Ave and also at 51st Ave and Union Hills.
Not sure what type of job you are looking for... Discover Card and American Express are both close by and have good benefits. The newspaper here is called The Arizona Republic. You may want to check that on-line for jobs.
The Phoenix zoo is a big, nice zoo about 45 min. from Midwestern and the Wildlife World zoo is a bit smaller and is about 30 min. from Midwestern ( no credit cards taken there). The Science Center is downtown Phoenix and has fun hands-on things for kids, but still would be a little old for your kiddo. The Botanical garden is next to the Phoenix zoo and is wonderful.
Lots of good Mexican food here as well. We like Macayo's at 59th Av & Bell. Margaritaville is fun at Glendale Ave & the 101 ( by the Cardinals Stadium).
Great hiking near Midwestern too at Thunderbird Park. Go north of Midwestern on 59th Ave, north of the 101 and the Park is on both sides of the road as well as parking on the back side of the park.