The problem with putting something in the oven while frozen is that the outer part tends to cook & burn, while the center stays frozen. She's better off thawing things the night before, as others have suggested. The enchiladas could probably be microwave-defrosted, but the length of time depends on the power of her microwave, so she'll actually know better than you how long it should cook. By the way, if you normally put a lot of beans and peppers in your enchiladas, you might want to re-think that if she will be breast-feeding. Sometimes gassy foods bother the baby.
You could consider quiches - in my experience, they freeze well. You could do spinach or quiche lorraine rather than broccoli or asparagus (gassier). Also chicken & rice should freeze well and she'd just have to add a little water to moisten up the rice. You could pick up a cookbook in your local library - sometimes there are some that specialize in "bulk" cooking where people make a lot and then freeze it in meal-sized portions. If your sister has a crock pot, that's another way to heat stuff up all day at a low temp - she can just throw it in the crock pot in the morning and it will be thawed and hot at dinner time.
You are great to do this for her - she will really appreciate it and it will be much more helpful than all the people who show up with gifts! (That part is FUN but it doesn't help much in the exhaustion department!)