Kat, there is a fabulous process called Non-Violent Communication (also called NVC and Compassionate Communication) that is effective for exactly this sort of problem. If you are truly fed up with this repeating pattern, I hope you will google those terms for descriptions, examples, and resources describing this process. These are tried and tested tools to help you break through to something far more satisfying and peaceful. And your husband doesn't even have to be using the techniques for them to work.
The difference in effective communication is that it doesn't confuse valid feelings, like anger, sadness, or happiness, with the thoughts and concepts we use to explain those feelings to ourselves or each other.
For example, you might feel too sad too talk, and intend to tell your husband as soon as you get hold of your emotions. If you had described your state in those words, he would probably have felt sympathy. The communication short circuited, apparently, when you said instead that you'd "tell him later," and didn't share the depth of your "upset." He felt perhaps a bit startled and angry, which he quickly interpreted to himself as a "feeling" of being rejected. According to NVC, "rejection" is not a feeling at all, it's an interpretation of feelings, perhaps based on previous unsuccessful communications that were never resolved. And that interpretation results in your husband's attitude toward you taking a dive.
This is a fascinating area to investigate, because it explains so much about why and how people react, often mistakenly. It helps us understand these tendencies in ourselves, too. What amazing freedom to get out from under all the confusing concepts we try to live with.
The other wonderful thing about NVC is that it teaches us how to listen with true empathy and respect, and then ASK for exactly that empathy and respect from the other person, not as a demand, but as a gentle request. People can hardly resist giving back the gift of honest caring you have just given them.
I have found this process to be life-changing, improving some extremely difficult family relationships, and keeping communication running smoothly in work and social relationships, as well. And I'm not even very good at it. (My husband and several folks in my religious community have also learned the process, and find it useful it in all sorts of situations.)
I can't recommend this process highly enough. I wish it were taught in schools – what a gift it would be to the next generation.