Jennifer is right - it IS a big deal.
He works hard, gets a check for his work, and gets days off from work. You work just as hard, with no check, and no days off. The fact that he has a job outside the home does not absolve him of any responsibility at home.
Unless he's in a body cast, there is absolutely no good reason for a grown man to leave his clothes on the floor, hair in the sink, or his plate on the table.
I have zero patience with this sort of behavior. I don't accept it from my child, and I certainly would not accept it from an adult. If he doesn't pick his clothes up, leave them where he dropped them. If he runs out of clean clothes, too damn bad. If he doesn't clean out the sink after he shaves,, leave the hair there. When goes to shave the next morning, and the sink is nasty, he'll get the message. If he doesn't take his plate to the sink, leave it on the table. Come dinner time the next night, serve the kids and yourself, and hand him the dirty plate from the night before. Tell him he gets his dinner after he washes his nasty plate. If he's going to act like a spoiled child, treat him like one. You expect your daughters to bring their dirty laundry to the hamper, don't you? You expect them to rinse out the sink after they brush their teeth, right? They are responsible for bringing their dishes to the kitchen after meals, aren't they? If a child can do these things, then an adult certainly can. Besides, it's his responsibility as a parent to set a good example.
You are supposed to be his partner, not his servant. You have daughters watching you. Do you want them to grow up thinking that it's their job to clean up other people's messes?