J.B.
You just have to tell the basic truth, like you have been with your son. We are also a his, hers and ours blended family, and my step-daughter has half brothers on her mother's side too. The older kids never asked a lot of questions (possibly because they lived it, so they know their own stories) but my middle son, age 7, asks questions all the time and I just answer whatever he asks and no more. Today he asked me what my oldest son's father's name is and what he looks like. He asked how old my son was when his father left and when I told him that he wasn't even born yet, he was pretty surprised. Then he asked me how long I was married to daddy and I said 8 years so he said "oh. So you were by yourself with just C____ for 5 years?" and I said yes and he moved on to something else.
The kids will be piecing together the puzzle for a long time as they get older and can grasp things. When my younger kids ask me why their dad isn't their brother's dad or why I'm not their sister's mother, I just tell them that when my son was born, I didn't know daddy yet and when my SD was born, daddy didn't know me yet. As you know, it's never a once and done conversation. You just have to be prepared to get questions out of the blue at any time and answer the best you can.